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Moves learnt by level up

Volcanion learns the following moves in Pokémon Sword & Shield at the levels specified.

Lv.	Move	Type	Cat.	Power	Acc.
1	Fire Spin	Fire		35	85
1	Water Gun	Water		40	100
6	Leer	Normal		—	100
12	Weather Ball	Normal		50	100
18	Flame Charge	Fire		50	100
24	Water Pulse	Water		60	100
30	Scary Face	Normal		—	100
36	Incinerate	Fire		60	100
42	Stomp	Normal		65	100
48	Scald	Water		80	100
54	Take Down	Normal		90	85
60	Haze	Ice		—	—
60	Mist	Ice		—	—
66	Hydro Pump	Water		110	80
72	Steam Eruption	Water		110	95
78	Flare Blitz	Fire		120	100
84	Overheat	Fire		130	90
90	Explosion	Normal		250	100

Egg moves

Volcanion does not learn any moves by breeding in Pokémon Sword & Shield.

Move Tutor moves

Volcanion can be taught these attacks in Pokémon Sword & Shield from move tutors (details):

Move	Type	Cat.	Power	Acc.
Scorching Sands	Ground		70	100

Moves learnt by TM

Volcanion is compatible with these Technical Machines in Pokémon Sword & Shield:

TM	Move	Type	Cat.	Power	Acc.
08	Hyper Beam	Normal		150	90
09	Giga Impact	Normal		150	90
11	Solar Beam	Grass		120	100
13	Fire Spin	Fire		35	85
20	Self-Destruct	Normal		200	100
21	Rest	Psychic		—	—
22	Rock Slide	Rock		75	90
24	Snore	Normal		50	100
25	Protect	Normal		—	—
26	Scary Face	Normal		—	100
32	Sandstorm	Rock		—	—
33	Rain Dance	Water		—	—
34	Sunny Day	Fire		—	—
38	Will-O-Wisp	Fire		—	85
39	Facade	Normal		70	100
43	Brick Break	Fighting		75	100
46	Weather Ball	Normal		50	100
53	Mud Shot	Ground		55	95
59	Fling	Dark		—	100
66	Thunder Fang	Electric		65	95
76	Round	Normal		60	100
81	Bulldoze	Ground		60	100
89	Misty Terrain	Fairy		—	—
98	Stomping Tantrum	Ground		75	100

Moves learnt by TR

Volcanion is compatible with these Technical Records in Pokémon Sword & Shield:

TR	Move	Type	Cat.	Power	Acc.
01	Body Slam	Normal		85	100
02	Flamethrower	Fire		90	100
03	Hydro Pump	Water		110	80
10	Earthquake	Ground		100	100
13	Focus Energy	Normal		—	—
15	Fire Blast	Fire		110	85
20	Substitute	Normal		—	—
22	Sludge Bomb	Poison		90	100
26	Endure	Normal		—	—
27	Sleep Talk	Normal		—	—
36	Heat Wave	Fire		95	90
39	Superpower	Fighting		120	100
43	Overheat	Fire		130	90
52	Gyro Ball	Steel		—	100
55	Flare Blitz	Fire		120	100
64	Focus Blast	Fighting		120	70
67	Earth Power	Ground		90	100
70	Flash Cannon	Steel		80	100
75	Stone Edge	Rock		100	80
78	Sludge Wave	Poison		95	100
79	Heavy Slam	Steel		—	100
84	Scald	Water		80	100
88	Heat Crash	Fire		—	100
98	Liquidation	Water		85	100
99	Body Press	Fighting		80	100